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On April 8, 2025, 12:02:35 PM UTC,
ckan_admin:
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Added resource O1910126.raw to Occurrence of nucleoside-bacteriohopanepolyol in high latitude soils: evidence of environmental controls on bacterial lipid membrane distributions
| f | 1 | { | f | 1 | { |
| 2 | "author": "Darci Rush (Royal Netherlands Institute for Sea | 2 | "author": "Darci Rush (Royal Netherlands Institute for Sea | ||
| 3 | Research)", | 3 | Research)", | ||
| 4 | "author_email": "darci.rush@nioz.nl", | 4 | "author_email": "darci.rush@nioz.nl", | ||
| 5 | "code": "7b.b.jj", | 5 | "code": "7b.b.jj", | ||
| 6 | "contributor": "Royal Netherlands Institute for Sea Research | 6 | "contributor": "Royal Netherlands Institute for Sea Research | ||
| 7 | (NIOZ)", | 7 | (NIOZ)", | ||
| 8 | "creator_user_id": "f4f66810-dfb9-487d-bc54-aaab2d6100ca", | 8 | "creator_user_id": "f4f66810-dfb9-487d-bc54-aaab2d6100ca", | ||
| 9 | "creators": | 9 | "creators": | ||
| 10 | \"Darci\",\"lastname\":\"Rush\",\"orcid\":null,\"affiliation\":\"Royal | 10 | \"Darci\",\"lastname\":\"Rush\",\"orcid\":null,\"affiliation\":\"Royal | ||
| 11 | Netherlands Institute for Sea | 11 | Netherlands Institute for Sea | ||
| 12 | e,\"contactemailaddress\":\"darci.rush@nioz.nl\",\"formatted\":\"Darci | 12 | e,\"contactemailaddress\":\"darci.rush@nioz.nl\",\"formatted\":\"Darci | ||
| 13 | Rush - Royal Netherlands Institute for Sea Research - ORCID: - | 13 | Rush - Royal Netherlands Institute for Sea Research - ORCID: - | ||
| 14 | Corresponding Author - darci.rush@nioz.nl\"}]", | 14 | Corresponding Author - darci.rush@nioz.nl\"}]", | ||
| 15 | "dataset_persistent_id": "DOI:10.25850/nioz/7b.b.jj", | 15 | "dataset_persistent_id": "DOI:10.25850/nioz/7b.b.jj", | ||
| 16 | "deposit_date": "2025-04-08", | 16 | "deposit_date": "2025-04-08", | ||
| 17 | "depositor": "Darci Rush (darci.rush@nioz.nl)", | 17 | "depositor": "Darci Rush (darci.rush@nioz.nl)", | ||
| 18 | "distribution_date": "2025-04-08", | 18 | "distribution_date": "2025-04-08", | ||
| 19 | "distributor": "Research Data Management(NIOZ Royal Netherlands | 19 | "distributor": "Research Data Management(NIOZ Royal Netherlands | ||
| 20 | Institute for Sea Research)", | 20 | Institute for Sea Research)", | ||
| 21 | "doi_date_published": "2025-04-08T13:51:52.123343", | 21 | "doi_date_published": "2025-04-08T13:51:52.123343", | ||
| 22 | "funding_references": "[{\"name\":\"NWO\",\"awardnumber\":\"213.176 | 22 | "funding_references": "[{\"name\":\"NWO\",\"awardnumber\":\"213.176 | ||
| 23 | \",\"awardtitle\":\"Nu-BHPs\",\"formatted\":\"NWO - 213.176 - | 23 | \",\"awardtitle\":\"Nu-BHPs\",\"formatted\":\"NWO - 213.176 - | ||
| 24 | Nu-BHPs\"}]", | 24 | Nu-BHPs\"}]", | ||
| 25 | "groups": [], | 25 | "groups": [], | ||
| 26 | "id": "885b861b-6e93-4878-8856-faef52905b49", | 26 | "id": "885b861b-6e93-4878-8856-faef52905b49", | ||
| 27 | "isopen": false, | 27 | "isopen": false, | ||
| 28 | "license_title": null, | 28 | "license_title": null, | ||
| 29 | "maintainer": "Darci", | 29 | "maintainer": "Darci", | ||
| 30 | "maintainer_email": "darci.rush@nioz.nl", | 30 | "maintainer_email": "darci.rush@nioz.nl", | ||
| 31 | "metadata_created": "2025-04-08T11:52:08.060260", | 31 | "metadata_created": "2025-04-08T11:52:08.060260", | ||
| n | 32 | "metadata_modified": "2025-04-08T12:02:28.853301", | n | 32 | "metadata_modified": "2025-04-08T12:02:35.555476", |
| 33 | "name": | 33 | "name": | ||
| 34 | occurrence-of-nucleoside-bacteriohopanepolyol-in-high-latitude-soils", | 34 | occurrence-of-nucleoside-bacteriohopanepolyol-in-high-latitude-soils", | ||
| 35 | "notes": "Recently, the analysis of non-derivatised | 35 | "notes": "Recently, the analysis of non-derivatised | ||
| 36 | bacteriohopanepolyols (BHPs) by ultra-high performance liquid | 36 | bacteriohopanepolyols (BHPs) by ultra-high performance liquid | ||
| 37 | chromatography-high resolution mass spectrometry (UHPLC-HRMS2) | 37 | chromatography-high resolution mass spectrometry (UHPLC-HRMS2) | ||
| 38 | revealed a broad structural diversity in this lipid class. Multiple | 38 | revealed a broad structural diversity in this lipid class. Multiple | ||
| 39 | unique BHPs with nucleoside-type polar head groups (Nu-BHPs) were | 39 | unique BHPs with nucleoside-type polar head groups (Nu-BHPs) were | ||
| 40 | identified in soils. Nu-BHPs had previously been identified in high | 40 | identified in soils. Nu-BHPs had previously been identified in high | ||
| 41 | abundances in soil organic matter, but only by analysing acetylated | 41 | abundances in soil organic matter, but only by analysing acetylated | ||
| 42 | BHPs, which hindered their structural elucidation. In this study, we | 42 | BHPs, which hindered their structural elucidation. In this study, we | ||
| 43 | apply the UHPLC-HRMS2direct analysis method for the first time to a | 43 | apply the UHPLC-HRMS2direct analysis method for the first time to a | ||
| 44 | soil transect to re-examine the distribution of Nu-BHPs, their | 44 | soil transect to re-examine the distribution of Nu-BHPs, their | ||
| 45 | environmental dependencies, and their proxy potential. The presence | 45 | environmental dependencies, and their proxy potential. The presence | ||
| 46 | and distribution of Nu-BHPs was examined in 17 surface soils along a | 46 | and distribution of Nu-BHPs was examined in 17 surface soils along a | ||
| 47 | ~800 km transect in northern Alaska. Our results indicate that certain | 47 | ~800 km transect in northern Alaska. Our results indicate that certain | ||
| 48 | Nu-BHPs show significant correlation with environmental parameters, | 48 | Nu-BHPs show significant correlation with environmental parameters, | ||
| 49 | such as temperature and soil pH. The variation in 9 Nu-BHPs is | 49 | such as temperature and soil pH. The variation in 9 Nu-BHPs is | ||
| 50 | captured using a novel ratio, and a regional calibration for warmest | 50 | captured using a novel ratio, and a regional calibration for warmest | ||
| 51 | quarter soil temperature (WQST) was developed using a linear | 51 | quarter soil temperature (WQST) was developed using a linear | ||
| 52 | regression approach (R2 = 0.72). Other calibrations developed for | 52 | regression approach (R2 = 0.72). Other calibrations developed for | ||
| 53 | summer air and mean annual temperatures also show strong positive | 53 | summer air and mean annual temperatures also show strong positive | ||
| 54 | correlations. As BHPs are ubiquitous in soils globally, this study | 54 | correlations. As BHPs are ubiquitous in soils globally, this study | ||
| 55 | highlights the potential benefit of complementing established organic | 55 | highlights the potential benefit of complementing established organic | ||
| 56 | proxies for soil pH and temperature (e.g., branched tetraether lipids) | 56 | proxies for soil pH and temperature (e.g., branched tetraether lipids) | ||
| 57 | with calibrations based on Nu-BHPs. Nevertheless, the mechanism behind | 57 | with calibrations based on Nu-BHPs. Nevertheless, the mechanism behind | ||
| 58 | the environmental dependencies of these BHPs remains unknown. Further | 58 | the environmental dependencies of these BHPs remains unknown. Further | ||
| 59 | work to explore the proxy potential as well as the bacterial sources | 59 | work to explore the proxy potential as well as the bacterial sources | ||
| 60 | of these lipids should be undertaken, for instance by sampling soils | 60 | of these lipids should be undertaken, for instance by sampling soils | ||
| 61 | along relevant (soil pH and temperature) gradients.", | 61 | along relevant (soil pH and temperature) gradients.", | ||
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| 65 | "approval_status": "approved", | 65 | "approval_status": "approved", | ||
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