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  "contributor": "NIOZ Royal Netherlands Institute for Sea Research",
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  "contributor": "NIOZ Royal Netherlands Institute for Sea Research",
            
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Netherlands Institute for Sea 
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Netherlands Institute for Sea 
            
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tactemailaddress\":\"szabina.karancz@nioz.nl\",\"formatted\":\"Szabina 
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tactemailaddress\":\"szabina.karancz@nioz.nl\",\"formatted\":\"Szabina 
            
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Karancz - Royal Netherlands Institute for Sea Research - ORCID: 
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Karancz - Royal Netherlands Institute for Sea Research - ORCID: 
            
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0000-0003-3433-3041 - Corresponding Author - 
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0000-0003-3433-3041 - Corresponding Author - 
            
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,\"lastname\":\"Uchikawa\",\"orcid\":null,\"affiliation\":\"Department 
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,\"lastname\":\"Uchikawa\",\"orcid\":null,\"affiliation\":\"Department 
            
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of Oceanography, SOEST, University of Hawaii at 
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of Oceanography, SOEST, University of Hawaii at 
            
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pondingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Joji 
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pondingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Joji 
            
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Uchikawa - Department of Oceanography, SOEST, University of Hawaii at 
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Uchikawa - Department of Oceanography, SOEST, University of Hawaii at 
            
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Manoa - ORCID: \"},{\"firstname\":\"Lennart J.\",\"lastname\":\"de 
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Manoa - ORCID: \"},{\"firstname\":\"Lennart J.\",\"lastname\":\"de 
            
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Nooijer\",\"orcid\":null,\"affiliation\":\"Royal Netherlands Institute 
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Nooijer\",\"orcid\":null,\"affiliation\":\"Royal Netherlands Institute 
            
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for Sea 
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for Sea 
            
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dingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Lennart 
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dingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Lennart 
            
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J. de Nooijer - Royal Netherlands Institute for Sea Research - ORCID: 
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J. de Nooijer - Royal Netherlands Institute for Sea Research - ORCID: 
            
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,\"lastname\":\"Wolthers\",\"orcid\":null,\"affiliation\":\"Department 
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,\"lastname\":\"Wolthers\",\"orcid\":null,\"affiliation\":\"Department 
            
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of Earth Sciences, Utrecht 
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of Earth Sciences, Utrecht 
            
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thor\":null,\"contactemailaddress\":null,\"formatted\":\"Mari\u00ebtte 
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thor\":null,\"contactemailaddress\":null,\"formatted\":\"Mari\u00ebtte 
            
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Wolthers - Department of Earth Sciences, Utrecht University - ORCID: 
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Wolthers - Department of Earth Sciences, Utrecht University - ORCID: 
            
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\"},{\"firstname\":\"Kyle 
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\"},{\"firstname\":\"Kyle 
            
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\",\"lastname\":\"Conner\",\"orcid\":null,\"affiliation\":\"Department 
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\",\"lastname\":\"Conner\",\"orcid\":null,\"affiliation\":\"Department 
            
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of Oceanography, SOEST, University of Hawaii at 
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of Oceanography, SOEST, University of Hawaii at 
            
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pondingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Kyle 
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pondingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Kyle 
            
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A. Conner - Department of Oceanography, SOEST, University of Hawaii at 
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A. Conner - Department of Oceanography, SOEST, University of Hawaii at 
            
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Manoa - ORCID: \"},{\"firstname\":\"Corinne G. 
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Manoa - ORCID: \"},{\"firstname\":\"Corinne G. 
            
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\",\"lastname\":\"Hite\",\"orcid\":null,\"affiliation\":\"Department 
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\",\"lastname\":\"Hite\",\"orcid\":null,\"affiliation\":\"Department 
            
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of Oceanography, SOEST, University of Hawaii at 
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of Oceanography, SOEST, University of Hawaii at 
            
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dingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Corinne 
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dingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Corinne 
            
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G.  Hite - Department of Oceanography, SOEST, University of Hawaii at 
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G.  Hite - Department of Oceanography, SOEST, University of Hawaii at 
            
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Manoa - ORCID: \"},{\"firstname\":\"Richard E. 
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Manoa - ORCID: \"},{\"firstname\":\"Richard E. 
            
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\",\"lastname\":\"Zeebe\",\"orcid\":null,\"affiliation\":\"Department 
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\",\"lastname\":\"Zeebe\",\"orcid\":null,\"affiliation\":\"Department 
            
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of Oceanography, SOEST, University of Hawaii at 
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of Oceanography, SOEST, University of Hawaii at 
            
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dingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Richard 
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dingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Richard 
            
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E.  Zeebe - Department of Oceanography, SOEST, University of Hawaii at 
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E.  Zeebe - Department of Oceanography, SOEST, University of Hawaii at 
            
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Manoa - ORCID: 
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Manoa - ORCID: 
            
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\",\"lastname\":\"Sharma\",\"orcid\":null,\"affiliation\":\"Department 
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\",\"lastname\":\"Sharma\",\"orcid\":null,\"affiliation\":\"Department 
            
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of Oceanography, SOEST, University of Hawaii at 
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of Oceanography, SOEST, University of Hawaii at 
            
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pondingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Shiv 
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pondingauthor\":null,\"contactemailaddress\":null,\"formatted\":\"Shiv 
            
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Sharma - Department of Oceanography, SOEST, University of Hawaii at 
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Sharma - Department of Oceanography, SOEST, University of Hawaii at 
            
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Manoa - ORCID: 
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Manoa - ORCID: 
            
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Jan\",\"lastname\":\"Reichart\",\"orcid\":null,\"affiliation\":\"Royal 
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Jan\",\"lastname\":\"Reichart\",\"orcid\":null,\"affiliation\":\"Royal 
            
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Netherlands Institute for Sea 
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Netherlands Institute for Sea 
            
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arch\",\"iscorrespondingauthor\":null,\"contactemailaddress\":null}]",
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arch\",\"iscorrespondingauthor\":null,\"contactemailaddress\":null}]",
            
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  "dataset_persistent_id": "DOI:10.25850/nioz/7b.b.yg",
            
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  "deposit_date": "2024-01-16",
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  "deposit_date": "2024-01-16",
            
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  "depositor": "Szabina Karancz",
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  "depositor": "Szabina Karancz",
            
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  "distribution_date": "2024-01-16",
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  "distribution_date": "2024-01-16",
            
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  "distributor": "Research Data Management(NIOZ Royal Netherlands 
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  "distributor": "Research Data Management(NIOZ Royal Netherlands 
            
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Institute for Sea Research)",
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Institute for Sea Research)",
            
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  "doi_date_published": "2024-01-16",
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  "doi_date_published": "2024-01-16",
            
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  "name": "7bbyg",
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  "name": "7bbyg",
            
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  "notes": "The sulfur over calcium ratio (S/Ca) in foraminiferal 
66
  "notes": "The sulfur over calcium ratio (S/Ca) in foraminiferal 
            
67
shells was recently proposed as a new and independent proxy for 
67
shells was recently proposed as a new and independent proxy for 
            
68
reconstructing marine inorganic carbon chemistry. This new approach 
68
reconstructing marine inorganic carbon chemistry. This new approach 
            
69
assumes that sulfur is incorporated into CaCO3 predominantly in the 
69
assumes that sulfur is incorporated into CaCO3 predominantly in the 
            
70
form of sulfate (SO42-) through lattice substitution for carbonate 
70
form of sulfate (SO42-) through lattice substitution for carbonate 
            
71
ions (CO32-), and that S/Ca thus reflects seawater [CO32-]. Although 
71
ions (CO32-), and that S/Ca thus reflects seawater [CO32-]. Although 
            
72
foraminiferal growth experiments validated this approach, field 
72
foraminiferal growth experiments validated this approach, field 
            
73
studies showed controversial results suggesting that the potential 
73
studies showed controversial results suggesting that the potential 
            
74
impact of [CO32-] may be overwritten by one or more parameters. Hence, 
74
impact of [CO32-] may be overwritten by one or more parameters. Hence, 
            
75
to better understand the inorganic processes involved, we here 
75
to better understand the inorganic processes involved, we here 
            
76
investigate S/Ca values in inorganically precipitated CaCO3 (S/Ca(cc)) 
76
investigate S/Ca values in inorganically precipitated CaCO3 (S/Ca(cc)) 
            
77
grown in solutions of CaCl2 - Na2CO3 - Na2SO4 - B(OH)3 - MgCl2. 
77
grown in solutions of CaCl2 - Na2CO3 - Na2SO4 - B(OH)3 - MgCl2. 
            
78
Experimental results indicate the dependence of sulfate partitioning 
78
Experimental results indicate the dependence of sulfate partitioning 
            
79
in CaCO3 on the carbon chemistry via changing pH and suggest that 
79
in CaCO3 on the carbon chemistry via changing pH and suggest that 
            
80
faster precipitation rates increase the partition coefficient for 
80
faster precipitation rates increase the partition coefficient for 
            
81
sulfur. Based on the positive correlation found between S/Ca(cc) and 
81
sulfur. Based on the positive correlation found between S/Ca(cc) and 
            
82
the concentration of only one aqueous sulfate species, [CaSO40](aq), 
82
the concentration of only one aqueous sulfate species, [CaSO40](aq), 
            
83
we here suggest a critical evaluation of this potential proxy. As 
83
we here suggest a critical evaluation of this potential proxy. As 
            
84
sulfate complexation seems to control sulfate uptake in inorganic 
84
sulfate complexation seems to control sulfate uptake in inorganic 
            
85
calcite, application as a proxy using foraminiferal calcite may be 
85
calcite, application as a proxy using foraminiferal calcite may be 
            
86
limited to periods for which seawater chemistry is well-constrained. 
86
limited to periods for which seawater chemistry is well-constrained. 
            
87
As foraminiferal calcite growth is modulated by inward Ca2+ flow to 
87
As foraminiferal calcite growth is modulated by inward Ca2+ flow to 
            
88
the site of calcification coupled to outward H+ pumping, sulfate 
88
the site of calcification coupled to outward H+ pumping, sulfate 
            
89
incorporation as CaSO40 ion-pair in the foraminifer\u2019s shell also 
89
incorporation as CaSO40 ion-pair in the foraminifer\u2019s shell also 
            
90
provides a mechanistic link for the observed relationship between 
90
provides a mechanistic link for the observed relationship between 
            
91
S/Ca(cc) and [CO32-].",
91
S/Ca(cc) and [CO32-].",
            
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      "display_name": "Sulfate incorporation",
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  "title": "Constraining sulfur incorporation in calcite using 
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controlled growth experiments",
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in calcite using controlled growth experiments\"",
            
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