Changes
On November 27, 2025, 10:15:34 AM UTC,
ckan_admin:
-
Added resource 130415_HyPy335C_10s-Centroided.cdf to Darci Rush
| f | 1 | { | f | 1 | { |
| 2 | "author": "Darci Rush (Royal Netherlands Institute for Sea | 2 | "author": "Darci Rush (Royal Netherlands Institute for Sea | ||
| 3 | Research)", | 3 | Research)", | ||
| 4 | "author_email": "darci.rush@nioz.nl", | 4 | "author_email": "darci.rush@nioz.nl", | ||
| 5 | "code": "7b.b.7j", | 5 | "code": "7b.b.7j", | ||
| 6 | "contributor": "Royal Netherlands Institute for Sea Research | 6 | "contributor": "Royal Netherlands Institute for Sea Research | ||
| 7 | (NIOZ)", | 7 | (NIOZ)", | ||
| 8 | "creator_user_id": "04853165-3f89-4016-9300-1ed632a64052", | 8 | "creator_user_id": "04853165-3f89-4016-9300-1ed632a64052", | ||
| 9 | "creators": | 9 | "creators": | ||
| 10 | e\":\"Rush\",\"orcid\":\"0000-0002-6567-4116\",\"affiliation\":\"Royal | 10 | e\":\"Rush\",\"orcid\":\"0000-0002-6567-4116\",\"affiliation\":\"Royal | ||
| 11 | Netherlands Institute for Sea | 11 | Netherlands Institute for Sea | ||
| 12 | e,\"contactemailaddress\":\"darci.rush@nioz.nl\",\"formatted\":\"Darci | 12 | e,\"contactemailaddress\":\"darci.rush@nioz.nl\",\"formatted\":\"Darci | ||
| 13 | Rush - Royal Netherlands Institute for Sea Research - ORCID: | 13 | Rush - Royal Netherlands Institute for Sea Research - ORCID: | ||
| 14 | 0000-0002-6567-4116 - Corresponding Author - darci.rush@nioz.nl\"}]", | 14 | 0000-0002-6567-4116 - Corresponding Author - darci.rush@nioz.nl\"}]", | ||
| 15 | "dataset_persistent_id": "DOI:10.25850/nioz/7b.b.7j", | 15 | "dataset_persistent_id": "DOI:10.25850/nioz/7b.b.7j", | ||
| 16 | "deposit_date": "2025-11-27", | 16 | "deposit_date": "2025-11-27", | ||
| 17 | "depositor": "Darci Rush (darci.rush@nioz.nl)", | 17 | "depositor": "Darci Rush (darci.rush@nioz.nl)", | ||
| 18 | "distribution_date": "2025-11-27", | 18 | "distribution_date": "2025-11-27", | ||
| 19 | "distributor": "Research Data Management(NIOZ Royal Netherlands | 19 | "distributor": "Research Data Management(NIOZ Royal Netherlands | ||
| 20 | Institute for Sea Research)", | 20 | Institute for Sea Research)", | ||
| 21 | "doi_date_published": "2025-11-27T11:14:32.465535", | 21 | "doi_date_published": "2025-11-27T11:14:32.465535", | ||
| 22 | "groups": [], | 22 | "groups": [], | ||
| 23 | "id": "c226037f-c7d5-44c3-b049-15d4e615e3a5", | 23 | "id": "c226037f-c7d5-44c3-b049-15d4e615e3a5", | ||
| 24 | "isopen": false, | 24 | "isopen": false, | ||
| 25 | "license_title": null, | 25 | "license_title": null, | ||
| 26 | "maintainer": "Darci", | 26 | "maintainer": "Darci", | ||
| 27 | "maintainer_email": "darci.rush@nioz.nl", | 27 | "maintainer_email": "darci.rush@nioz.nl", | ||
| 28 | "metadata_created": "2025-11-27T10:14:41.313453", | 28 | "metadata_created": "2025-11-27T10:14:41.313453", | ||
| n | 29 | "metadata_modified": "2025-11-27T10:15:33.343120", | n | 29 | "metadata_modified": "2025-11-27T10:15:34.394476", |
| 30 | "name": "darci-rush", | 30 | "name": "darci-rush", | ||
| 31 | "notes": "Anaerobic ammonium oxidation (anammox) is an important | 31 | "notes": "Anaerobic ammonium oxidation (anammox) is an important | ||
| 32 | process in modern global nitrogen cycling. However, the contribution | 32 | process in modern global nitrogen cycling. However, the contribution | ||
| 33 | of anammox to ancient nitrogen biogeochemical cycles cannot currently | 33 | of anammox to ancient nitrogen biogeochemical cycles cannot currently | ||
| 34 | be accounted for because the most characteristic lipid biomarkers of | 34 | be accounted for because the most characteristic lipid biomarkers of | ||
| 35 | anammox bacteria, ladderane lipids containing concatenated series of | 35 | anammox bacteria, ladderane lipids containing concatenated series of | ||
| 36 | cyclobutane moieties, do not preserve as such into the catagenetic | 36 | cyclobutane moieties, do not preserve as such into the catagenetic | ||
| 37 | window in the sedimentary record. Alternative lipid biomarkers that | 37 | window in the sedimentary record. Alternative lipid biomarkers that | ||
| 38 | are more resistant to degradation are needed by the geochemical | 38 | are more resistant to degradation are needed by the geochemical | ||
| 39 | community to investigate the presence anammox in high maturity | 39 | community to investigate the presence anammox in high maturity | ||
| 40 | sediments and inform on past marine oxygen depletion, nitrogen | 40 | sediments and inform on past marine oxygen depletion, nitrogen | ||
| 41 | cycling, and the formation of organic rich sediment such as black | 41 | cycling, and the formation of organic rich sediment such as black | ||
| 42 | shale deposits. Here, we describe novel cyclic hydrocarbons produced | 42 | shale deposits. Here, we describe novel cyclic hydrocarbons produced | ||
| 43 | by the simulated thermal maturation of anammox bacterial biomass. | 43 | by the simulated thermal maturation of anammox bacterial biomass. | ||
| 44 | Alkyl branched tricyclic hydrocarbons were present in pyrolysates | 44 | Alkyl branched tricyclic hydrocarbons were present in pyrolysates | ||
| 45 | generated by hydrous pyrolysis experiments at temperatures >200 | 45 | generated by hydrous pyrolysis experiments at temperatures >200 | ||
| 46 | \u00b0C, in the window of oil generation. Two-dimensional gas | 46 | \u00b0C, in the window of oil generation. Two-dimensional gas | ||
| 47 | chromatography-mass spectrometry revealed that these artificial | 47 | chromatography-mass spectrometry revealed that these artificial | ||
| 48 | maturation experiments generated multiple series of cyclic | 48 | maturation experiments generated multiple series of cyclic | ||
| 49 | hydrocarbons. A representative product was isolated by preparative gas | 49 | hydrocarbons. A representative product was isolated by preparative gas | ||
| 50 | chromatography, but was shown to be composed of two co-eluting | 50 | chromatography, but was shown to be composed of two co-eluting | ||
| 51 | components. Their structures were partially identified, by way of | 51 | components. Their structures were partially identified, by way of | ||
| 52 | two-dimensional nuclear magnetic resonance (NMR), to be | 52 | two-dimensional nuclear magnetic resonance (NMR), to be | ||
| 53 | 4-octyl-tricyclo[7.3.0.02,8]dodecanes with the three concatenated | 53 | 4-octyl-tricyclo[7.3.0.02,8]dodecanes with the three concatenated | ||
| 54 | rings comprising of 7, 4, and 5 carbons. This ring assemblage was | 54 | rings comprising of 7, 4, and 5 carbons. This ring assemblage was | ||
| 55 | further confirmed through NMR and mass spectral comparisons with four | 55 | further confirmed through NMR and mass spectral comparisons with four | ||
| 56 | synthesized model compounds. The isolated components had a stable | 56 | synthesized model compounds. The isolated components had a stable | ||
| 57 | carbon isotopic composition similarly depleted in 13C as the ladderane | 57 | carbon isotopic composition similarly depleted in 13C as the ladderane | ||
| 58 | fatty acids of the original anammox biomass, consistent with a | 58 | fatty acids of the original anammox biomass, consistent with a | ||
| 59 | ladderane lipid source. The C20 hydrocarbons could have formed from | 59 | ladderane lipid source. The C20 hydrocarbons could have formed from | ||
| 60 | thermal ether cleavage and ring-opening of the C20-[5]- or | 60 | thermal ether cleavage and ring-opening of the C20-[5]- or | ||
| 61 | [3]-ladderane glycerol ether, common membrane lipids of anammox | 61 | [3]-ladderane glycerol ether, common membrane lipids of anammox | ||
| 62 | bacteria. Molecular mechanic calculations were used to generate the | 62 | bacteria. Molecular mechanic calculations were used to generate the | ||
| 63 | relative structural stability of stereoisomers and the possible | 63 | relative structural stability of stereoisomers and the possible | ||
| 64 | conversion steps to the formation of these components. These indicated | 64 | conversion steps to the formation of these components. These indicated | ||
| 65 | that the 7-4-5 components were the result of the breakdown and | 65 | that the 7-4-5 components were the result of the breakdown and | ||
| 66 | rearrangement of bonds in the cyclobutane rings from | 66 | rearrangement of bonds in the cyclobutane rings from | ||
| 67 | biosynthetically-derived 4-4-4-4-4 ladderane lipids. These components | 67 | biosynthetically-derived 4-4-4-4-4 ladderane lipids. These components | ||
| 68 | were not detected in thermally mature sediment and rocks screened | 68 | were not detected in thermally mature sediment and rocks screened | ||
| 69 | using conventional GC-MS analysis, however, by using more advanced | 69 | using conventional GC-MS analysis, however, by using more advanced | ||
| 70 | chromatography methods these lipids may be still be helpful biomarkers | 70 | chromatography methods these lipids may be still be helpful biomarkers | ||
| 71 | for assessing past anammox in ancient sediments and crude oils.", | 71 | for assessing past anammox in ancient sediments and crude oils.", | ||
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| 74 | "organization": { | 74 | "organization": { | ||
| 75 | "approval_status": "approved", | 75 | "approval_status": "approved", | ||
| 76 | "created": "2024-10-22T06:06:56.074257", | 76 | "created": "2024-10-22T06:06:56.074257", | ||
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| 79 | "image_url": | 79 | "image_url": | ||
| 80 | z.nl/application/files/1216/8924/5333/NIOZ-logo_witte_randi-2023.svg", | 80 | z.nl/application/files/1216/8924/5333/NIOZ-logo_witte_randi-2023.svg", | ||
| 81 | "is_organization": true, | 81 | "is_organization": true, | ||
| 82 | "name": "nioz", | 82 | "name": "nioz", | ||
| 83 | "state": "active", | 83 | "state": "active", | ||
| 84 | "title": "Royal Netherlands Institute for Sea Research", | 84 | "title": "Royal Netherlands Institute for Sea Research", | ||
| 85 | "type": "organization" | 85 | "type": "organization" | ||
| 86 | }, | 86 | }, | ||
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